Extraction of Pacitan Sweet Orange Peel Pectin as a Bioadsorbent on the Adsorption Process of Fe Metal in FeCl3 Solution
DOI:
https://doi.org/10.70609/g-tech.v9i3.7085Keywords:
Pectin, Extraction, AdsorptionAbstract
One alternative to treating waste that contains heavy metals is by bioadsorption process from natural materials as adsorbents. In this study, Pacitan sweet orange peel raw material was used as a FeCl3 metal bioadsorbent. This study aims to obtain pectin as a bioadsorbent for Fe metal in FeCl3 solution with the influence of extraction time and temperature on pectin extraction. In this study, pectin was extracted using the direct extraction method with HCl solvent. To prove the characteristics of pectin, FTIR analysis was conducted by observing the C=O group contained in pectin. Atomic Adsorption Spectrophotometer (AAS) analysis was then used to perform pectin adsorption in a FeCl3 solution. The research results show that optimum conditions are achieved at a temperature of 80°C, a contact time of 90 minutes with the addition of a pectin mass of 90 mg obtained an adsorption efficiency of 60.52%. From the isotherm adsorption analysis, Freundlich isotherm was applied to the adsorption of FeCl3 metal with a determination coefficient (R2) of 0.968.
References
Alamineh, E. A. (2018). Extraction of Pectin From Orange Peels and Characterizing It's Pyshical and Chemical Properties. American Journal of Applied Chemistry, 51-56.
Andrini, A. (2021). Teknologi Inovatif Jeruk Sehat Nusantara. Bogor: IPB Press.
Apriyanti, H. (2018). Karakterisasi Isoterm Adsorpsi dai Ion Logam Besi (Fe) Pada Tanah di Kota Bengkulu. Jurnal Pendidikan dan Ilmu Kimia, 14-19.
Ashraf, M. M. (2010). Study of Banana Peel (Musa sapientum) as a Cationic Biosorben. American-Eurasian Journal Agric & Environ, 7-17.
Azizi, M. H. (2020). Koefisien Perpindahan Massa pada Ekstraksi Polisakarida dari Biji Asam Jawa dengan Pelarut NaOH . Journal of Chemical and Process Engineering, 8-13.
Damanik, D. A. (2019). Ekstraksi Pektin dari Limbah Kulit Jeruk (Citrus sinensis) dengan Metode Ekstraksi Gelombang Ultrasonik Menggunakan Pelarut Asam Klorida (HCl). Jurnal Teknik Kimia USU, 85-89.
Daud, N. Z. (2019). pH-Dependent Yield and Physicochemical Properties of Pectin Isolated From Citrus Maxima. International Journal of Technology, 1131-1139.
Fatmawati, N. (2018). Bioadsorpsi Fe(II) Oleh Kulit Buah Jeruk Citrus nobilis Lour, var microcarpa Termodifikasi Ca(OH)2. Indonesian Journal of Pure and Applied Chemistry, 98-113.
Griffiths, Peter R. (2007). Fourier Transform Infrared Spectrometry Second Edition. New Jersey: John Wiley & Sons, Inc.
Ismadji, S. (2021). Adsorpsi Pada Fase Cair . Surabaya: Universitas Katolik Widya Mandala Surabaya.
Latupeirissa, J. (2019). Ekstraksi dan Karakterisasi Pektin Kulit Jeruk Manis Kisar (Citrus Sp.). Indo. J. Chem. Res., 53-60.
Maulida, F. E. (2023). Ekstraksi dan Karakterisasi Pektin dari Limbah Kulit Jeruk Limau (Citrus amblycarpa). Jurnal Kimia Mulawarman, 56-63.
Miri, N. S. (2022). Review : Kajian Persamaan Isoterm Langmuir dan Freundlich pada Adsorpsi Logam Berat Fe(II) dengan Zeolit dan Karbon Aktif dari Biomassa. Jurnal Kimia dan Rekayasa, 58-71.
Murtando, H. (2016). Identifikasi Karakter Morfologi dan Anatomi Tanaman Jeruk Lokal (Citrus Sp) di Desa Karya Agung dan Karya Abadi Kecamatan Taopa Kabupaten Parigi Moutong. Agrotekbis, 642-649.
Nkafamiya, I. I. (2019). Physicochemical Characterization and FTIR Spectroscopic Study of Pectin from Bombax ceiba (Bamta) Fruit. Pakistan Journal of Scientific and Industrial Research. 82-91.
Rahayu, W. P. (2021). Ekstraksi Pektin dari Kulit Jeruk dan Kulit Pisang sebagai Bioseoben pada Proses Adsorpsi Logam Berat Fe. Serambi Engineering, 1899-1907.
Rizki, A. (2019). Pengaruh Waktu Kontak dan Massa Adsorben Biji Asam Jawa (Tamarindus indica) dengan Aktivator H3PO4 terhadap Kapasitas Adsorpsi Zat Warna Methylene Blue. Jurnal Teknik Kimia USU, 54-60.
Solika, N. (2017). Bioadsorpsi Pb(II) Menggunakan Kulit Jeruk Siam (Citrus reticulata). Jurnal Akademia Kimia, 160-164.
Tuhuloula. (2013). Karakterisasi Pektin Dengan Memanfaatkan Limbah Kulit Pisang Menggunakan Metode Ekstraksi . Konversi, 21-27.
Vasdazara, O. L. (2018). Pengaruh Penambahan Serat Cangkang Kelapa Sawit (Palm Kernel Fiber) Terhadap Sifat Mekanik dan Stabilitas Termal Komposit Epoksi/Serat Cangkang Kelapa Sawit. Jurnal Teknik ITS, 119-123.
Yoakhim. (2021). Produksi Pektin Dari Kulit Jeruk Nipis (Citrus aurantifolis S) Dengan Interaksi Suhu dan Lama Ektraksi. Jurnal Transdisiplin Pertanian (Budidaya Tanaman, Perkebunan. Kehutanan, Peternakan, Perikanan), Sosial dan Ekonomi, 737-742.
Zahrotun, E. (2013). Pengaruh Suhu dan Waktu Terhadap Hasil Ekstraksi Pektin Dari Kulit Buah Nanas. Simposium Nasional RAPI XII , 39-43.
Zhao, G. (2011). Sorption of Heavy Metals Ions from Aqueous Solution : A Review, The Open Colloidal Science Journal , 19-31
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